Record Information
Version1.0
StatusDetected and Quantified
Creation Date2021-05-14 23:43:10 UTC
Update Date2022-08-31 06:25:41 UTC
Metabolite IDMMDBc0006574
Metabolite Identification
Common NameMicrocin J25
Description3-[18,57-dibenzyl-9,63-bis(butan-2-yl)-5,8,11,14,17,20,23,26,35,38,41,44,47,50,53,56,59,62,65-nonadecahydroxy-3-(1-hydroxyethyl)-60-(hydroxymethyl)-21,54-bis[(4-hydroxyphenyl)methyl]-36-[(1H-imidazol-5-yl)methyl]-42-methyl-2,32-dioxo-15,33-bis(propan-2-yl)-1,4,7,10,13,16,19,22,25,31,34,37,40,43,46,49,52,55,58,61,64-henicosaazatricyclo[64.3.0.0²⁷,³¹]nonahexaconta-4,7,10,13,16,19,22,25,34,37,40,43,46,49,52,55,58,61,64-nonadecaen-24-yl]propanoic acid belongs to the class of organic compounds known as polypeptides. These are peptides containing ten or more amino acid residues. Based on a literature review very few articles have been published on 3-[18,57-dibenzyl-9,63-bis(butan-2-yl)-5,8,11,14,17,20,23,26,35,38,41,44,47,50,53,56,59,62,65-nonadecahydroxy-3-(1-hydroxyethyl)-60-(hydroxymethyl)-21,54-bis[(4-hydroxyphenyl)methyl]-36-[(1H-imidazol-5-yl)methyl]-42-methyl-2,32-dioxo-15,33-bis(propan-2-yl)-1,4,7,10,13,16,19,22,25,31,34,37,40,43,46,49,52,55,58,61,64-henicosaazatricyclo[64.3.0.0²⁷,³¹]nonahexaconta-4,7,10,13,16,19,22,25,34,37,40,43,46,49,52,55,58,61,64-nonadecaen-24-yl]propanoic acid.
Structure
Synonyms
ValueSource
3-[18,57-Dibenzyl-9,63-bis(butan-2-yl)-5,8,11,14,17,20,23,26,35,38,41,44,47,50,53,56,59,62,65-nonadecahydroxy-3-(1-hydroxyethyl)-60-(hydroxymethyl)-21,54-bis[(4-hydroxyphenyl)methyl]-36-[(1H-imidazol-5-yl)methyl]-42-methyl-2,32-dioxo-15,33-bis(propan-2-yl)-1,4,7,10,13,16,19,22,25,31,34,37,40,43,46,49,52,55,58,61,64-henicosaazatricyclo[64.3.0.0,]nonahexaconta-4,7,10,13,16,19,22,25,34,37,40,43,46,49,52,55,58,61,64-nonadecaen-24-yl]propanoateGenerator
Molecular FormulaC101H139N23O27
Average Mass2107.357
Monoisotopic Mass2106.021076308
IUPAC Name3-[18,57-dibenzyl-9,63-bis(butan-2-yl)-3-(1-hydroxyethyl)-60-(hydroxymethyl)-21,54-bis[(4-hydroxyphenyl)methyl]-36-[(1H-imidazol-5-yl)methyl]-42-methyl-2,5,8,11,14,17,20,23,26,32,35,38,41,44,47,50,53,56,59,62,65-henicosaoxo-15,33-bis(propan-2-yl)-1,4,7,10,13,16,19,22,25,31,34,37,40,43,46,49,52,55,58,61,64-henicosaazatricyclo[64.3.0.0^{27,31}]nonahexacontan-24-yl]propanoic acid
Traditional Name3-[18,57-dibenzyl-3-(1-hydroxyethyl)-60-(hydroxymethyl)-21,54-bis[(4-hydroxyphenyl)methyl]-36-(3H-imidazol-4-ylmethyl)-15,33-diisopropyl-42-methyl-2,5,8,11,14,17,20,23,26,32,35,38,41,44,47,50,53,56,59,62,65-henicosaoxo-9,63-bis(sec-butyl)-1,4,7,10,13,16,19,22,25,31,34,37,40,43,46,49,52,55,58,61,64-henicosaazatricyclo[64.3.0.0^{27,31}]nonahexacontan-24-yl]propanoic acid
CAS Registry NumberNot Available
SMILES
CCC(C)C1NC(=O)CNC(=O)C(NC(=O)C(CC2=CC=CC=C2)NC(=O)C(CC2=CC=C(O)C=C2)NC(=O)C(CCC(O)=O)NC(=O)C2CCCN2C(=O)C(NC(=O)C(CC2=CN=CN2)NC(=O)CNC(=O)C(C)NC(=O)CNC(=O)CNC(=O)CNC(=O)C(CC2=CC=C(O)C=C2)NC(=O)C(CC2=CC=CC=C2)NC(=O)C(CO)NC(=O)C(NC(=O)C2CCCN2C(=O)C(NC(=O)CNC1=O)C(C)O)C(C)CC)C(C)C)C(C)C
InChI Identifier
InChI=1S/C101H139N23O27/c1-11-55(7)84-98(148)108-50-80(134)119-86(58(10)126)101(151)124-38-20-26-74(124)96(146)122-85(56(8)12-2)99(149)117-72(51-125)94(144)116-68(39-59-21-15-13-16-22-59)90(140)113-67(41-61-27-31-64(127)32-28-61)88(138)106-46-76(130)103-45-75(129)104-47-77(131)110-57(9)87(137)105-48-78(132)111-71(43-63-44-102-52-109-63)93(143)121-83(54(5)6)100(150)123-37-19-25-73(123)95(145)112-66(35-36-81(135)136)89(139)114-69(42-62-29-33-65(128)34-30-62)91(141)115-70(40-60-23-17-14-18-24-60)92(142)120-82(53(3)4)97(147)107-49-79(133)118-84/h13-18,21-24,27-34,44,52-58,66-74,82-86,125-128H,11-12,19-20,25-26,35-43,45-51H2,1-10H3,(H,102,109)(H,103,130)(H,104,129)(H,105,137)(H,106,138)(H,107,147)(H,108,148)(H,110,131)(H,111,132)(H,112,145)(H,113,140)(H,114,139)(H,115,141)(H,116,144)(H,117,149)(H,118,133)(H,119,134)(H,120,142)(H,121,143)(H,122,146)(H,135,136)
InChI KeyTVZWTTNULXZYTK-UHFFFAOYSA-N