Record Information
Version1.0
StatusDetected and Quantified
Creation Date2021-11-17 23:51:17 UTC
Update Date2022-08-31 17:38:52 UTC
Metabolite IDMMDBc0030030
Metabolite Identification
Common Name5-O-(1-Carboxyvinyl)-3-phosphoshikimate
Description5-o-(1-carboxyvinyl)-3-phosphoshikimate is a member of the chemical class known as Organophosphate Esters. These are organic compounds containing phosphoric acid ester functional group. The shikimate pathway enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) is the target of the broad spectrum herbicide glyphosate. (PMID 19211556 ) 5-Enolpyruvylshikimate-3-phosphate (EPSP) synthase (AroA) is a key enzyme in the aromatic amino acid biosynthetic pathway in microorganisms and plants, and is the target of the herbicide glyphosate. (PMID 16469313 )
Structure
Synonyms
ValueSource
O5-(1-Carboxyvinyl)-3-phosphoshikimateChEBI
O5-(1-Carboxyvinyl)-3-phosphoshikimic acidGenerator
5-O-(1-Carboxyvinyl)-3-phosphoshikimic acidGenerator
5-O-(1-Carboxyvinyl)-3-phosphoshikimateChEBI, Generator
Molecular FormulaC10H13O10P
Average Mass324.178
Monoisotopic Mass324.024633148
IUPAC Name(3R,4S,5R)-5-[(1-carboxyeth-1-en-1-yl)oxy]-4-hydroxy-3-(phosphonooxy)cyclohex-1-ene-1-carboxylic acid
Traditional Name(3R,4S,5R)-5-[(1-carboxyeth-1-en-1-yl)oxy]-4-hydroxy-3-(phosphonooxy)cyclohex-1-ene-1-carboxylic acid
CAS Registry Number89771-75-5
SMILES
O[C@H]1[C@@H](CC(=C[C@H]1OP(O)(O)=O)C(O)=O)OC(=C)C(O)=O
InChI Identifier
InChI=1S/C10H13O10P/c1-4(9(12)13)19-6-2-5(10(14)15)3-7(8(6)11)20-21(16,17)18/h3,6-8,11H,1-2H2,(H,12,13)(H,14,15)(H2,16,17,18)/t6-,7-,8+/m1/s1
InChI KeyQUTYKIXIUDQOLK-PRJMDXOYSA-N