MiMeDB: Showing metabocard for 4-(gamma-L-glutamylamino)butanal (MMDBc0054257)

Record Information

Version

2.0

Status

Detected and Quantified

Creation Date

2022-06-05 23:01:59 UTC

Update Date

2025-10-07 16:08:26 UTC

Metabolite ID

MMDBc0054257

Metabolite Identification

Common Name

4-(gamma-L-glutamylamino)butanal

Description

4-(gamma-L-glutamylamino)butanal is a metabolite belonging to the class of amino acid derivatives. There is limited literature available on this compound, indicating that further research may be needed to fully understand its biological significance and potential applications.

Structure

MOL SDF PDB SMILES InChI


  Mrv0541 10101211122D          

 16 15  0  0  0  0            999 V2000
   -2.3349    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0493    0.7145    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.2375    0.7145    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.5230    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6204    0.7145    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7638    1.1270    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9520    1.1270    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.1914    0.7145    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6664    0.7145    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9520    1.9520    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9059    1.1270    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   -4.4783    0.7145    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1914   -0.1105    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.3809    1.1270    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.6664   -0.1105    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.9520    0.3020    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  0  0  0  0
  4  3  1  0  0  0  0
  5  1  1  0  0  0  0
  6  2  1  0  0  0  0
  7  3  1  0  0  0  0
  8  4  1  0  0  0  0
  9  7  1  0  0  0  0
  7 10  1  1  0  0  0
 11  5  1  4  0  0  0
 11  8  2  0  0  0  0
 12  6  2  0  0  0  0
 13  8  1  0  0  0  0
 14  9  2  0  0  0  0
 15  9  1  0  0  0  0
  7 16  1  1  0  0  0
M  END
> <DATABASE_ID>
MMDBc0054257

> <DATABASE_NAME>
MIME

> <SMILES>
[H][C@](N)(CCC(O)=NCCCC=O)C(O)=O

> <INCHI_IDENTIFIER>
InChI=1S/C9H16N2O4/c10-7(9(14)15)3-4-8(13)11-5-1-2-6-12/h6-7H,1-5,10H2,(H,11,13)(H,14,15)/t7-/m0/s1

> <INCHI_KEY>
JZNLEPLZUABCSQ-ZETCQYMHSA-N

> <FORMULA>
C9H16N2O4

> <MOLECULAR_WEIGHT>
216.2343

> <EXACT_MASS>
216.11100701

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_AVERAGE_POLARIZABILITY>
22.381354714474742

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S)-2-amino-4-[(4-oxobutyl)-C-hydroxycarbonimidoyl]butanoic acid

> <ALOGPS_LOGP>
-2.80

> <JCHEM_LOGP>
-3.2268933633905434

> <ALOGPS_LOGS>
-2.15

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
0

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
7.202788354046516

> <JCHEM_PKA_STRONGEST_ACIDIC>
2.1416223195936634

> <JCHEM_PKA_STRONGEST_BASIC>
9.715881526684305

> <JCHEM_POLAR_SURFACE_AREA>
112.98

> <JCHEM_REFRACTIVITY>
53.14190000000001

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
1.54e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(2S)-2-amino-4-[(4-oxobutyl)-C-hydroxycarbonimidoyl]butanoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 10-OCT-12   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   10-OCT-12         0                                  
HETATM    1  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       0.000   0.000   0.000  0.00  0.00           C+0
HETATM   10  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   11  N   UNK     0       0.000   0.000   0.000  0.00  0.00           N+0
HETATM   12  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   13  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   14  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   15  O   UNK     0       0.000   0.000   0.000  0.00  0.00           O+0
HETATM   16  H   UNK     0       0.000   0.000   0.000  0.00  0.00           H+0
CONECT    1    2    5                                                       
CONECT    2    1    6                                                       
CONECT    3    4    7                                                       
CONECT    4    3    8                                                       
CONECT    5    1   11                                                       
CONECT    6    2   12                                                       
CONECT    7    3    9   10   16                                             
CONECT    8    4   11   13                                                  
CONECT    9    7   14   15                                                  
CONECT   10    7                                                            
CONECT   11    5    8                                                       
CONECT   12    6                                                            
CONECT   13    8                                                            
CONECT   14    9                                                            
CONECT   15    9                                                            
CONECT   16    7                                                            
MASTER        0    0    0    0    0    0    0    0   16    0   30    0
END

Synonyms

Value	Source
(2S)-2-Ammonio-5-oxo-5-[(4-oxobutyl)amino]pentanoate	ChEBI
4-(gamma-L-Glutamylamino)butanal	ChEBI
(2S)-2-Ammonio-5-oxo-5-[(4-oxobutyl)amino]pentanoic acid	Generator
4-(g-L-Glutamylamino)butanal	Generator
4-(Γ-L-glutamylamino)butanal	Generator
g-Glutamyl-g-aminobutyraldehyde zwitterion	Generator
Γ-glutamyl-γ-aminobutyraldehyde zwitterion	Generator
gamma-Glutamyl-gamma-aminobutyraldehyde	ChEBI
g-Glutamyl-g-aminobutyraldehyde	Generator
γ-glutamyl-γ-aminobutyraldehyde	Generator

Molecular Formula

C₉H₁₆N₂O₄

Average Mass

216.2343

Monoisotopic Mass

216.11100701

IUPAC Name

(2S)-2-amino-4-[(4-oxobutyl)-C-hydroxycarbonimidoyl]butanoic acid

Traditional Name

(2S)-2-amino-4-[(4-oxobutyl)-C-hydroxycarbonimidoyl]butanoic acid

CAS Registry Number

Not Available

SMILES

[H][C@](N)(CCC(O)=NCCCC=O)C(O)=O

InChI Identifier

InChI=1S/C9H16N2O4/c10-7(9(14)15)3-4-8(13)11-5-1-2-6-12/h6-7H,1-5,10H2,(H,11,13)(H,14,15)/t7-/m0/s1

InChI Key

JZNLEPLZUABCSQ-ZETCQYMHSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as glutamine and derivatives. Glutamine and derivatives are compounds containing glutamine or a derivative thereof resulting from reaction of glutamine at the amino group or the carboxy group, or from the replacement of any hydrogen of glycine by a heteroatom.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Amino acids, peptides, and analogues

Direct Parent

Glutamine and derivatives

Alternative Parents

Substituents

Glutamine or derivatives
Alpha-amino acid
L-alpha-amino acid
Fatty amide
Fatty acyl
Fatty acid
N-acyl-amine
Alpha-hydrogen aldehyde
Carboxamide group
Amino acid
Secondary carboxylic acid amide
Carboxylic acid
Monocarboxylic acid or derivatives
Aldehyde
Organonitrogen compound
Organooxygen compound
Primary amine
Primary aliphatic amine
Hydrocarbon derivative
Organic oxide
Organopnictogen compound
Carbonyl group
Amine
Organic oxygen compound
Organic nitrogen compound
Aliphatic acyclic compound

Molecular Framework

Aliphatic acyclic compounds

External Descriptors

non-proteinogenic L-alpha-amino acid (CHEBI:61521 )
L-glutamine derivative (CHEBI:61521 )
aldehyde (CHEBI:61521 )

Functional Ontology

Not Available

Physical Properties

State

Expected Solid

Predicted Properties

Property	Value	Source
Water Solubility	1.54 g/L	ALOGPS
logP	-2.8	ALOGPS
logP	-3.2	ChemAxon
logS	-2.2	ALOGPS
pKa (Strongest Acidic)	2.14	ChemAxon
pKa (Strongest Basic)	9.72	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	112.98 Å²	ChemAxon
Rotatable Bond Count	8	ChemAxon
Refractivity	53.14 m³·mol⁻¹	ChemAxon
Polarizability	22.38 Å³	ChemAxon
Number of Rings	0	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Spectra

Spectrum Type	Description	Splash Key	Deposition Date	View
Predicted GC-MS	Predicted GC-MS Spectrum - GC-MS (TMS_2_1) - 70eV, Positive	Not Available	2022-08-08	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Positive	splash10-0079-9620000000-bfbb737e33f759f64917	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Positive	splash10-000i-9100000000-fec8d8af7e2fd43d74af	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Positive	splash10-0a4u-9000000000-2c84c134274f31a7c254	2019-02-22	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 10V, Negative	splash10-014i-0890000000-2a2c0fd0946623c2e1a5	2019-02-23	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 20V, Negative	splash10-00kb-4920000000-801199aebcda0b1d6caf	2019-02-23	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - 40V, Negative	splash10-0006-9200000000-df6e56c7aa9feec9ee69	2019-02-23	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)		2022-08-20	View Spectrum

Chromatographic Retention Times and Retention Indices

Retention Times

Chromatography Type	Technique	Column	Deposition Date	Retention Time (s)
Liquid Chromatography	HILIC	Waters Acquity UPLC-BEH Amide column (eluted)	2025-10-24	476.2
Liquid Chromatography	HILIC	Accucore 150 Amide HILIC (eluted)	2025-10-24	377.8
Liquid Chromatography	Reversed-phase	Hypersil Gold 1.9 µm C18 (void)	2025-10-24	50.6
Liquid Chromatography	Reversed-phase	Agilent Zorbax Eclipse Plus C18 (2.1 mm x 150 mm, 3.5 um) (eluted)	2025-10-24	247.8
Liquid Chromatography	Reversed-phase	XBridge C18 3.5u 2.1x50 mm (eluted)	2025-10-24	269.4
Liquid Chromatography	Reversed-phase	Ascentis Express C18 (void)	2025-10-24	235.4
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	391.0
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	759.7
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC (eluted)	2025-10-24	406.1
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (eluted)	2025-10-24	149.3
Liquid Chromatography	HILIC	Merck SeQuant ZIC-HILIC (eluted)	2025-10-24	491.3
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC HSS T3 C18 (void)	2025-10-24	162.5
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	69.6
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	349.6
Liquid Chromatography	HILIC	Merck SeQuant ZIC-pHILIC column (eluted)	2025-10-24	735.2
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	55.0
Liquid Chromatography	Reversed-phase	Waters ACQUITY UPLC BEH C18 (eluted)	2025-10-24	199.5
Liquid Chromatography	Reversed-phase	Kinetex Core-Shell C18 2.6 um, 3.0 x 100 mm, Phenomenex (eluted)	2025-10-24	615.4
Liquid Chromatography	Reversed-phase	Waters Atlantis T3 (2.1 x 150 mm, 5 um) (eluted)	2025-10-24	561.9

Retention Indices

Chromatography Type	Peak Label	SMILES	Stationary Phase	Deposition Date	Retention Index
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_1	C[Si](C)(C)OC(CC[C@H](N)C(=O)O)=NCCCC=O	standard non polar	2025-10-24	1904.02
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_2	C[Si](C)(C)OC(=O)[C@@H](N)CCC(O)=NCCCC=O	standard non polar	2025-10-24	1768.86
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_3	C[Si](C)(C)OC=CCCN=C(O)CC[C@H](N)C(=O)O	standard non polar	2025-10-24	2064.08
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_4	C[Si](C)(C)N[C@@H](CCC(O)=NCCCC=O)C(=O)O	standard non polar	2025-10-24	2111.4
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_5	C[Si](C)(C)OC(=O)[C@@H](N)CCC(=NCCCC=O)O[Si](C)(C)C	standard non polar	2025-10-24	1654.36
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_6	C[Si](C)(C)OC=CCCN=C(CC[C@H](N)C(=O)O)O[Si](C)(C)C	standard non polar	2025-10-24	1645.7
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_7	C[Si](C)(C)N[C@@H](CCC(=NCCCC=O)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	2424.47
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_8	C[Si](C)(C)OC=CCCN=C(O)CC[C@H](N)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1616.97
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_9	C[Si](C)(C)N[C@@H](CCC(O)=NCCCC=O)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	1848.68
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_10	C[Si](C)(C)N[C@@H](CCC(O)=NCCC=CO[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1973.67
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_11	C[Si](C)(C)N([C@@H](CCC(O)=NCCCC=O)C(=O)O)[Si](C)(C)C	standard non polar	2025-10-24	1749.31
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_12	C[Si](C)(C)OC=CCCN=C(CC[C@H](N)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2368.33
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_13	C[Si](C)(C)N[C@@H](CCC(=NCCCC=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2282.57
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_14	C[Si](C)(C)N[C@@H](CCC(=NCCC=CO[Si](C)(C)C)O[Si](C)(C)C)C(=O)O	standard non polar	2025-10-24	1777.45
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_15	C[Si](C)(C)OC(CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NCCCC=O	standard non polar	2025-10-24	1718.59
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_16	C[Si](C)(C)N[C@@H](CCC(O)=NCCC=CO[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2033.94
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_17	C[Si](C)(C)OC(=O)[C@H](CCC(O)=NCCCC=O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1403.61
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_18	C[Si](C)(C)OC=CCCN=C(O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	1950.71
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_19	C[Si](C)(C)N[C@@H](CCC(=NCCC=CO[Si](C)(C)C)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard non polar	2025-10-24	2352.77
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_20	C[Si](C)(C)OC(=O)[C@H](CCC(=NCCCC=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2458.06
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_21	C[Si](C)(C)OC=CCCN=C(CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	1257.69
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_22	C[Si](C)(C)OC=CCCN=C(O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard non polar	2025-10-24	2299.17
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_23	C[Si](C)(C)OC=CCCN=C(CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)O[Si](C)(C)C	standard non polar	2025-10-24	2422.59
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_1	C[Si](C)(C)OC(CC[C@H](N)C(=O)O)=NCCCC=O	standard polar	2025-10-24	2081.59
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_2	C[Si](C)(C)OC(=O)[C@@H](N)CCC(O)=NCCCC=O	standard polar	2025-10-24	2296.87
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_3	C[Si](C)(C)OC=CCCN=C(O)CC[C@H](N)C(=O)O	standard polar	2025-10-24	2038.11
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_4	C[Si](C)(C)N[C@@H](CCC(O)=NCCCC=O)C(=O)O	standard polar	2025-10-24	1697.07
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_5	C[Si](C)(C)OC(=O)[C@@H](N)CCC(=NCCCC=O)O[Si](C)(C)C	standard polar	2025-10-24	1928.0
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_6	C[Si](C)(C)OC=CCCN=C(CC[C@H](N)C(=O)O)O[Si](C)(C)C	standard polar	2025-10-24	1985.89
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_7	C[Si](C)(C)N[C@@H](CCC(=NCCCC=O)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2221.47
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_8	C[Si](C)(C)OC=CCCN=C(O)CC[C@H](N)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2258.85
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_9	C[Si](C)(C)N[C@@H](CCC(O)=NCCCC=O)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2273.69
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_10	C[Si](C)(C)N[C@@H](CCC(O)=NCCC=CO[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	2081.88
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_11	C[Si](C)(C)N([C@@H](CCC(O)=NCCCC=O)C(=O)O)[Si](C)(C)C	standard polar	2025-10-24	2296.83
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_12	C[Si](C)(C)OC=CCCN=C(CC[C@H](N)C(=O)O[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	1127.21
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_13	C[Si](C)(C)N[C@@H](CCC(=NCCCC=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2120.57
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_14	C[Si](C)(C)N[C@@H](CCC(=NCCC=CO[Si](C)(C)C)O[Si](C)(C)C)C(=O)O	standard polar	2025-10-24	3231.7
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_15	C[Si](C)(C)OC(CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)=NCCCC=O	standard polar	2025-10-24	1957.41
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_16	C[Si](C)(C)N[C@@H](CCC(O)=NCCC=CO[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	1819.94
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_17	C[Si](C)(C)OC(=O)[C@H](CCC(O)=NCCCC=O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1799.63
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_18	C[Si](C)(C)OC=CCCN=C(O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1978.52
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_19	C[Si](C)(C)N[C@@H](CCC(=NCCC=CO[Si](C)(C)C)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	standard polar	2025-10-24	2406.65
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_20	C[Si](C)(C)OC(=O)[C@H](CCC(=NCCCC=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	1384.58
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_21	C[Si](C)(C)OC=CCCN=C(CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2445.51
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_22	C[Si](C)(C)OC=CCCN=C(O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C	standard polar	2025-10-24	825.699
Gas Chromatography	4-(gamma-L-glutamylamino)butanal_TMS_23	C[Si](C)(C)OC=CCCN=C(CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)O[Si](C)(C)C	standard polar	2025-10-24	2608.77

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Not Available

Tissue Locations

Not Available

Associated OMIM IDs

114500 (Colorectal cancer)
610247 (Eosinophilic esophagitis)

Human Proteins and Enzymes

Protein ID	Protein Name	Protein Type	Uniprot ID	Species

Human Pathways

Pathways

Name	SMPDB/PathBank

Microbial Pathways

Pathways

Not Available

Metabolic Reactions

Reactions

This table shows at most 20 reactions. For the full list of associated reactions:

See All Associated Reactions

Reaction ID	Precursor	Product	Enzyme	Reaction Type	Data Source	Reference

Health Effects and Bioactivity

Health Outcome/Bioactivity	Metabolite Response/Effect	Evidence Type	Host and Biospecimen	Data Source	Reference

Microbial Sources

Superkingdom/Kingdom	Phylum	Total species	Hosts and Body Sites	Microbial Links
Bacteria	Proteobacteria	1

Exposure Sources

Other Exposures

Source Type	Data Source	Reference

Host Biospecimen and Location

Host and Biospecimen	Status	Mean	Std	Min	Max	Units	Age	Sex	Health Condition	Data Source	Reference

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

C15700

BioCyc ID

GAMMA-GLUTAMYL-GAMMA-AMINOBUTYRALDEH

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

23724544

PDB ID

Not Available

ChEBI ID

61508

Food Biomarker Ontology

Not Available

CMMC Knowledgebase

Not Available

General References

Bansal P, Morgat A, Axelsen KB, Muthukrishnan V, Coudert E, Aimo L, Hyka-Nouspikel N, Gasteiger E, Kerhornou A, Neto TB, Pozzato M, Blatter MC, Ignatchenko A, Redaschi N, Bridge A: Rhea, the reaction knowledgebase in 2022. Nucleic Acids Res. 2022 Jan 7;50(D1):D693-D700. doi: 10.1093/nar/gkab1016. [PubMed:34755880 ]

Showing metabocard for 4-(gamma-L-glutamylamino)butanal (MMDBc0054257)

MOL for #<Metabolite:0x00007f9af253f838>

3D MOL for #<Metabolite:0x00007f9af253f838>

3D SDF for #<Metabolite:0x00007f9af253f838>

3D-SDF for #<Metabolite:0x00007f9af253f838>

PDB for #<Metabolite:0x00007f9af253f838>

3D PDB for #<Metabolite:0x00007f9af253f838>

SMILES for #<Metabolite:0x00007f9af253f838>

INCHI for #<Metabolite:0x00007f9af253f838>

Structure for #<Metabolite:0x00007f9af253f838>

3D Structure for #<Metabolite:0x00007f9af253f838>