Reactions | Reaction ID | Precursor | Product | Enzyme | Reaction Type | Data Source | Reference |
---|
MMDBr0013076 | Acetyl-CoA | 3,6,7,9-tetrahydroxy-3-methyl-2,3-dihydro-1H-naphtho[2,1-b]pyran-1-one | Non-reducing polyketide synthase phnA | Synthesis | RHEA | 34755880 | MMDBr0013077 | Acetyl-CoA | 3,6,7,9-tetrahydroxy-3-methyl-2,3-dihydro-1H-naphtho[2,1-b]pyran-1-one | Non-reducing polyketide synthase phnA | Synthesis | RHEA | 34755880 | MMDBr0013219 | 3,6,7,9-tetrahydroxy-3-methyl-2,3-dihydro-1H-naphtho[2,1-b]pyran-1-one | 2,3,4,7,9-pentahydroxy-6-methyl-1H-phenalen-1-one | FAD-dependent monooxygenase phnB | Oxygenation | RHEA | 34755880 | MMDBr0013220 | 3,6,7,9-tetrahydroxy-3-methyl-2,3-dihydro-1H-naphtho[2,1-b]pyran-1-one | 2,3,4,7,9-pentahydroxy-6-methyl-1H-phenalen-1-one | FAD-dependent monooxygenase phnB | Oxygenation | RHEA | 34755880 | MMDBr0017255 | 2,3,4,7,9-pentahydroxy-6-methyl-1H-phenalen-1-one | 2,4,7,9-tetrahydroxy-6-methyl-8-(2-methylbut-3-en-2-yl)-1-oxo-1H-phenalen-3-ol | Prenyltransferase phnF | Synthesis; Reverse C-prenylation of phenalenone | RHEA | 34755880 | MMDBr0017256 | 2,3,4,7,9-pentahydroxy-6-methyl-1H-phenalen-1-one | 2,4,7,9-tetrahydroxy-6-methyl-8-(2-methylbut-3-en-2-yl)-1-oxo-1H-phenalen-3-ol | Prenyltransferase phnF | Synthesis; Reverse C-prenylation of phenalenone | RHEA | 34755880 | MMDBr0017257 | 2,4,7,9-tetrahydroxy-6-methyl-8-(2-methylbut-3-en-2-yl)-1-oxo-1H-phenalen-3-ol | (2'R)-atrovenetin | Hydroalkoxylation enzyme phnH | Not Available | RHEA | 34755880 | MMDBr0017258 | 2,4,7,9-tetrahydroxy-6-methyl-8-(2-methylbut-3-en-2-yl)-1-oxo-1H-phenalen-3-ol | (2'R)-atrovenetin | Hydroalkoxylation enzyme phnH | Not Available | RHEA | 34755880 | MMDBr0017259 | (2'R)-atrovenetin | deoxyherqueinone | O-methyltransferase phnC | Methylation | RHEA | 34755880 | MMDBr0017260 | (2'R)-atrovenetin | deoxyherqueinone | O-methyltransferase phnC | Methylation | RHEA | 34755880 | MMDBr0017261 | deoxyherqueinone | Water | Oxidoreductase phnG | Redox reaction | RHEA | 34755880 | MMDBr0017262 | deoxyherqueinone | Water | Oxidoreductase phnG | Redox reaction | RHEA | 34755880 |
|
---|