Reactions | Reaction ID | Precursor | Product | Enzyme | Reaction Type | Data Source | Reference |
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MMDBr0014244 | 4-hydroxy-4-methyl-2-oxoglutarate | Pyruvic acid | 4-hydroxy-4-methyl-2-oxoglutarate aldolase cghB | Aldol addition (or reverse) | RHEA | 34755880 | MMDBr0014245 | Pyruvic acid | 4-hydroxy-4-methyl-2-oxoglutarate | 4-hydroxy-4-methyl-2-oxoglutarate aldolase cghB | Aldol addition (or reverse) | RHEA | 34755880 | MMDBr0017657 | (2S,4S)-4-hydroxy-4-methylglutamic acid | (2S)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Trans-enoyl reductase cghC | Reduction; Synthesis | RHEA | 34755880 | MMDBr0017658 | (2S,4S)-4-hydroxy-4-methylglutamic acid | (2S)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Trans-enoyl reductase cghC | Reduction; Synthesis | RHEA | 34755880 | MMDBr0017659 | (2S)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Sch 210792 | Diels-Alderase cghA | Diels–Alder reaction | RHEA | 34755880 | MMDBr0017660 | (2S)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Sch 210792 | Diels-Alderase cghA | Diels–Alder reaction | RHEA | 34755880 | MMDBr0017667 | (2S,4R)-4-hydroxy-4-methylglutamic acid | (2R)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Trans-enoyl reductase tasC | Reduction | RHEA | 34755880 | MMDBr0017668 | (2S,4R)-4-hydroxy-4-methylglutamic acid | (2R)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Trans-enoyl reductase tasC | Reduction | RHEA | 34755880 | MMDBr0017669 | (2R)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Sch 210971 | Diels-Alderase tas3 | Diels–Alder reaction | RHEA | 34755880 | MMDBr0017670 | (2R)-3-[(2S)-3,5-dioxo-4-[(2E,4R,6R,8E,10E,12E)-4,6,12-trimethyltetradeca-2,8,10,12-tetraenoyl]pyrrolidin-2-yl]-2-hydroxy-2-methylpropanoic acid | Sch 210971 | Diels-Alderase tas3 | Diels–Alder reaction | RHEA | 34755880 |
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