| MMDBr0015062 | 10-deoxymethynolide | YC-17 | 10-deoxymethynolide desosaminyltransferase | Desosaminyltransferase | RHEA | 34755880 |
| MMDBr0015080 | dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucose | dTDP-alpha-D-desosamine | dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucopyranose N,N-dimethyltransferase | Methylation | RHEA | 34755880 |
| MMDBr0015081 | dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucose | dTDP-alpha-D-desosamine | dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucopyranose N,N-dimethyltransferase | Methylation | RHEA | 34755880 |
| MMDBr0015699 | alpha-Ketoglutarate | dTDP-3-dehydro-4,6-dideoxy-alpha-D-glucose | dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucose transaminase | Transfer of amino group | RHEA | 34755880 |
| MMDBr0015872 | (S)-Methylmalonyl-CoA | Carbon dioxide | Narbonolide/10-deoxymethynolide synthase PikA1, modules 1 and 2 | Synthesis | RHEA | 34755880 |
| MMDBr0015887 | (S)-Methylmalonyl-CoA | 10-deoxymethynolide | Narbonolide/10-deoxymethynolide synthase PikA1, modules 1 and 2 | Synthesis | RHEA | 34755880 |
| MMDBr0024995 | S-Adenosylmethionine | Hydrogen Ion | dTDP-4-amino-4,6-dideoxy-D-glucose ammonia-lyase | Non-hydrolytic bond cleavage (or its reversal) | RHEA | 34755880 |
| MMDBr0024996 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
| MMDBr0025000 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
| MMDBr0025001 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
| MMDBr0025002 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
| MMDBr0025003 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
| MMDBr0025004 | Hydrogen Ion | Water | Cytochrome P450 monooxygenase PikC | Oxygenation | RHEA | 34755880 |
