Record Information
Version1.0
StatusDetected and Quantified
Creation Date2021-11-18 01:48:05 UTC
Update Date2022-08-31 18:24:24 UTC
Metabolite IDMMDBc0031757
Metabolite Identification
Common Name4-Amino-4-deoxy-alpha-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphate
Description4-Amino-4-deoxy-alpha-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphate is an intermediate in LPS synthesis. It is a substrate for Undecaprenyl-phosphate 4-deoxy-4-formamido-L-arabinose transferase which catalyzes the reaction UDP-4-deoxy-4-formamido-beta-L-arabinose + di-trans,octa-cis-undecaprenyl phosphate = UDP + 4-deoxy-4-formamido-alpha-L-arabinose di-trans,octa-cis-undecaprenyl phosphate.
Structure
Synonyms
ValueSource
Undecaprenyl phosphate alpha-L-ara4fnChEBI
4-Deoxy-4-formamido-alpha-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphateKegg
Undecaprenyl phosphate a-L-ara4fnGenerator
Undecaprenyl phosphate α-L-ara4fnGenerator
Undecaprenyl phosphoric acid a-L-ara4fnGenerator
Undecaprenyl phosphoric acid alpha-L-ara4fnGenerator
Undecaprenyl phosphoric acid α-L-ara4fnGenerator
4-Deoxy-4-formamido-a-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphateGenerator
4-Deoxy-4-formamido-a-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphoric acidGenerator
4-Deoxy-4-formamido-alpha-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphoric acidGenerator
4-Deoxy-4-formamido-α-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphateGenerator
4-Deoxy-4-formamido-α-L-arabinopyranosyl ditrans,octacis-undecaprenyl phosphoric acidGenerator
4-Amino-4-deoxy-a-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphateGenerator
4-Amino-4-deoxy-a-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphoric acidGenerator
4-Amino-4-deoxy-alpha-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphoric acidGenerator
4-Amino-4-deoxy-α-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphateGenerator
4-Amino-4-deoxy-α-L-arabinopyranosyl di-trans,octa-cis-undecaprenyl phosphoric acidGenerator
Molecular FormulaC61H100NO8P
Average Mass1006.4224
Monoisotopic Mass1005.718655693
IUPAC NameN-[(3S,4S,5R,6S)-4,5-dihydroxy-6-{[hydroxy({[(2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E,38E)-3,7,11,15,19,23,27,31,35,39,43-undecamethyltetratetraconta-2,6,10,14,18,22,26,30,34,38,42-undecaen-1-yl]oxy})phosphoryl]oxy}oxan-3-yl]carboximidic acid
Traditional NameN-[(3S,4S,5R,6S)-4,5-dihydroxy-6-({hydroxy[(2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E,38E)-3,7,11,15,19,23,27,31,35,39,43-undecamethyltetratetraconta-2,6,10,14,18,22,26,30,34,38,42-undecaen-1-yl]oxyphosphoryl}oxy)oxan-3-yl]carboximidic acid
CAS Registry NumberNot Available
SMILES
OC=N[C@@]1([H])CO[C@@]([H])(OP(O)(=O)OC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(\C)CC\C([H])=C(/C)CC\C([H])=C(/C)CCC=C(C)C)[C@@](O)([H])[C@]1(O)[H]
InChI Identifier
InChI=1S/C61H100NO8P/c1-47(2)23-13-24-48(3)25-14-26-49(4)27-15-28-50(5)29-16-30-51(6)31-17-32-52(7)33-18-34-53(8)35-19-36-54(9)37-20-38-55(10)39-21-40-56(11)41-22-42-57(12)43-44-69-71(66,67)70-61-60(65)59(64)58(45-68-61)62-46-63/h23,25,27,29,31,33,35,37,39,41,43,46,58-61,64-65H,13-22,24,26,28,30,32,34,36,38,40,42,44-45H2,1-12H3,(H,62,63)(H,66,67)/b48-25+,49-27+,50-29-,51-31-,52-33-,53-35-,54-37-,55-39-,56-41-,57-43-/t58-,59-,60+,61-/m0/s1
InChI KeyKDTATMYQJZYGGT-CRHUQJHVSA-N